Electric arc synthesis of titanium carbide using carbon obtained from thermal conversion of waste from the power industry

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The work presents for the first time the results of obtaining titanium carbide using a vacuum-free electric arc method using various types of biocarbon obtained by classical pyrolysis of biomass waste, such as tangerine peel, pomelo peel, banana peel, pine nut shells, walnut shells. Analysis of X-ray diffraction patterns of the synthesized materials showed the repeatability of the experiment with the receipt of diffraction maxima indicating the formation of a cubic structure of titanium carbide. An analysis of the thermal oxidation of the resulting powders showed that up to a thousand degrees the process proceeds quite slowly, but with increasing temperature the oxidation rate increases significantly. It has been established that during thermal heating in an oxidizing environment, the mass of the studied titanium carbide powders obtained using various types of carbon increases, which is confirmed by thermogravimetric analysis.

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Sobre autores

A. Svinukhova

National Research Tomsk Polytechnic Universityl

Autor responsável pela correspondência
Email: aag109@tpu.ru

Инженерная школа энергетики

Rússia, Tomsk, 634050

S. Yankovsky

National Research Tomsk Polytechnic Universityl

Email: jankovsky@tpu.ru

Инженерная школа энергетики

Rússia, Tomsk, 634050

A. Misyukova

National Research Tomsk Polytechnic Universityl

Email: adm14@tpu.ru

Инженерная школа энергетики

Rússia, Tomsk, 634050

A. Pak

National Research Tomsk Polytechnic Universityl

Email: ayapak@tpu.ru

Инженерная школа энергетики

Rússia, Tomsk, 634050

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2. Fig. 1. Results of scanning electron microscopy of carbon residue obtained by thermal conversion of the initial biomass: (a) carbon from mandarin peel; (b) carbon from pomelo peel; (c) carbon from banana peel; (d) carbon from cedar nut shell; (e) carbon from walnut shell.

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3. Fig. 2. TG (a), DSC (b), DTG (c) data for the oxidation process of the studied TiC samples obtained with the addition of carbon from biomass (medium – air, 100 ml/min), heating rate of 10 ° C/min, temperature range from 100 to 1000 °C).

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4. Fig. 3. Results of X-ray diffractometry of titanium carbide synthesis products.

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5. Fig. 4. Typical images of high-speed video recording of the oxidation and combustion process of the studied titanium carbide samples. Gorenje

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