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Аннотация

Исследована серия однокомпонентных катализаторов на основе комплексов палладия с фосфин-тиоэфирными лигандами в полимеризации этилена, а также сополимеризации этилена с норборненом. Установлено влияние условий реакции (природы растворителя, концентрации катализатора, температуры реакции) на характеристики продуктов (со-)полимеризации. Строение продуктов (со-)полимеризации этилена изучено с использованием 1Н, 13С ЯМР-спектроскопии. Применение фосфин-тиоэфирных комплексов в качестве катализаторов полимеризации этилена приводит к образованию низкомолекулярных продуктов. Выбор типа катализатора существенно влияет на состав и микроструктуру продуктов сополимеризации этилена с норборненом.

Авторлар туралы

G. Karpov

A. V. Topchiev Institute of Petrochemical Synthesis RAS

Email: karpov@ips.ac.ru
119991, GSP-1, Moscow, Leninsky Ave., 29, building 2

M. Bermeshev

A. V. Topchiev Institute of Petrochemical Synthesis RAS

Хат алмасуға жауапты Автор.
Email: karpov@ips.ac.ru
119991, GSP-1, Moscow, Leninsky Ave., 29, building 2

Әдебиет тізімі

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